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Microdamage study of granite under thermomechanical coupling based on the particle flow code

《结构与土木工程前沿（英文）》   页码 1413-1427 doi: 10.1007/s11709-023-0953-2

摘要： The thermomechanical coupling of rocks refers to the interaction between the mechanical and thermodynamic behaviors of rocks induced by temperature changes. The study of this coupling interaction is essential for understanding the mechanical and thermodynamic properties of the surrounding rocks in underground engineering. In this study, an improved temperature-dependent linear parallel bond model is introduced under the framework of a particle flow simulation. A series of numerical thermomechanical coupling tests are then conducted to calibrate the micro-parameters of the proposed model by considering the mechanical behavior of the rock under different thermomechanical loadings. Good agreement between the numerical results and experimental data are obtained, particularly in terms of the compression, tension, and elastic responses of granite. With this improved model, the thermodynamic response and underlying cracking behavior of a deep-buried tunnel under different thermal loading conditions are investigated and discussed in detail.

关键词： thermomechanical coupling effect     granite     improved linear parallel bond model     thermal property     particle flow code    

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Continuous modeling of soil morphology —thermomechanical behavior of embankment dams

Bettina ALBERS, Krzysztof WILMANSKI

《结构与土木工程前沿（英文）》 2011年 第5卷 第1期   页码 11-23 doi: 10.1007/s11709-010-0081-7

摘要： Macroscopic modeling of soils is based on a number of properties that refer to the mesoscopic morphology. The most fundamental parameters of this art are: 1) coupling parameters between partial stresses of components and deformations of components, 2) porosities, 3) saturation, and 4) permeability and diffusivity, tortuosity. The main aim of this paper is to present in juxtaposition continuous one-, two-, and three-component models of geomaterials appearing in construction of embankment dams. In particular, the above mentioned features, especially saturation with water and seepage problems, modeling of fluidization yielding piping, and generalizations of the Darcy law and changes of porosity, are presented.

关键词： thermomechanical modeling     soil morphology     saturation     porosity    

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Effect of alkyl nitrite decomposition on catalytic performance of CO coupling reaction over supported

Zhenhua LI, Weihan WANG, Dongxue YIN, Jing LV, Xinbin MA

《化学科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 410-414 doi: 10.1007/s11705-012-1213-5

摘要： The syntheses of dimethyl oxalate (DMO) and diethyl oxalate (DEO) by CO coupling reaction in gaseous phase were investigated in a fixed bed reactor over Pd-Fe/Al O catalyst. The catalytic performance was characterized by CO conversion, space-time yield (STY) and selectivity of DMO (or DEO). The results showed that over Pd-Fe/Al O catalyst, the STY of DMO was higher than that of DEO under the same reaction conditions. The optimum reaction temperatures for synthesizing DMO and DEO were 403 K and 393 K, respectively, at the molar ratio 1 ∶ 1 of alkyl nitrite to CO. The difference in synthesizing DMO and DEO on the same catalyst was attributed to the decomposition performances of methyl nitrite (MN) and ethyl nitrite (EN), as density functional theory (DFT) calculation showed that EN decomposed more easily than MN.

关键词： palladium     CO coupling     dialkyl oxalate     alkyl nitrite     decomposition    

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An extended thermo-mechanically coupled algorithm for simulation of superelasticity and shape memory effect

S. HASHEMI,H. AHMADIAN,S. MOHAMMADI

《结构与土木工程前沿（英文）》 2015年 第9卷 第4期   页码 466-477 doi: 10.1007/s11709-015-0300-3

摘要： Thermo-mechanical coupling in shape memory alloys is a very complicated phenomenon. The heat generation/absorption during forward/reverse transformation can lead to temperature-dependent variation of its mechanical behavior in the forms of superelasticity and shape memory effect. However, unlike the usual assumption, slow loading rate cannot guarantee an isothermal process. A two-dimensional thermo-mechanically coupled algorithm is proposed based on the original model of Lagoudas to efficiently model both superelasticity and shape memory effects and the influence of various strain rates, aspect ratios and boundary conditions. To implement the coupled model into a finite element code, a numerical staggered algorithm is employed. A number of simulations are performed to verify the proposed approach with available experimental and numerical data and to assess its efficiency in solving complex SMA problems.

关键词： shape memory alloy     thermo-mechanical coupling     superplasticity     shape memory effect    

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北京市城乡节能节水政策中长期耦合效果分析

刘耕源,胡俊梅,杨志峰

《中国工程科学》 2019年 第21卷 第5期   页码 120-129 doi: 10.15302/J-SSCAE-2019.05.007

摘要：

本文基于长期能源可替代规划系统模型（LEAP）与水资源评价和规划模型（WEAP）建立了城市的能水耦合模型，设立情景分析探讨北京市未来不同措施下城乡的节能/ 节水以及其耦合效果，并对结果进行敏感性分析。模型结果表明，未来北京市能源消费总量将逐年缓慢增长；按预测的供水能力则不会出现供需短缺。“十三五”期间节水政策的总节能量为1.003×106 tce，节能政策的节水量达到2.76×108 m3。居民生活、服务业、建筑业、传统制造业的能源需求值与水需求值具有较好的相关性，是重要的能水耦合部门。对于不同情景不同时期的节能/ 节水效果而言，产业结构优化政策在短期可表现出较好的节能潜力；农业部门的灌溉技术革新与种植结构优化情景，在短期具有较好的节能与节水效果。对于能水节约的协同效应，其在服务业与工业部门节能情景中较明显；对于同一个部门的政策，调控用能强度的情景能水协同节约效应较明显。

关键词： 北京市城乡     节能节水     政策耦合分析    

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Simulation of steel beam under ceiling jet based on a wind–fire–structure coupling model

《结构与土木工程前沿（英文）》 2023年 第17卷 第1期   页码 78-98 doi: 10.1007/s11709-022-0936-8

摘要： For localized fires, it is necessary to consider the thermal and mechanical responses of building elements subject to uneven heating under the influence of wind. In this paper, the thermomechanical phenomena experienced by a ceiling jet and I-beam in a structural fire were simulated. Instead of applying the concept of adiabatic surface temperature (AST) to achieve fluid–structure coupling, this paper proposes a new computational fluid dynamics–finite element method numerical simulation that combines wind, fire, thermal, and structural analyses. First, to analyze the velocity and temperature distributions, the results of the numerical model and experiment were compared in windless conditions, showing good agreement. Vortices were found in the local area formed by the upper and lower flanges of the I-beam and the web, generating a local high-temperature zone and enhancing the heat transfer of convection. In an incoming-flow scenario, the flame was blown askew significantly; the wall temperature was bimodally distributed in the axial direction. The first temperature peak was mainly caused by radiative heat transfer, while the second resulted from convective heat transfer. In terms of mechanical response, the yield strength degradation in the highest-temperature region in windless conditions was found to be significant, thus explaining the stress distribution of steel beams in the fire field. The mechanical response of the overall elements considering the incoming flows was essentially elastic.

关键词： CFD–FEM coupling     steel beam     wind     ceiling jet     numerical heat transfer    

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Polymer nanocomposites for microactuation and magneto-electric transduction

Kaori YUSE, Benoit GUIFFARD, Rabah BELOUADAH, Lionel PETIT, Laurence SEVEYRAT, Daniel GUYOMAR

《机械工程前沿（英文）》 2009年 第4卷 第3期   页码 350-354 doi: 10.1007/s11465-009-0056-3

摘要： In the last decade, electroactive polymers have attracted much attention especially because of their very actuating capabilities. Large strain is experimentally observed, but under quite high electrical field, which can be a severe drawback for actuating applications. First part of the present paper is concerned with the reduction of applied field onto electroactive polymer films to get a given strain level. Polyurethane (PU) films filled with carbon black (CB) nanoparticles exhibit relatively high strain level under a field of only 12.5 kV/mm. The simple easy-to-make method solution cast method was applied. Even though the generated stress level is still quite low, the present work shows high strain level under quite low field appliance by easy manufacturing, lightweight, and flexible polymer film. Besides, another interest of the present paper is in magneto-elasto-electric effect of a polymer film filled with some magnetic nano particles. Films filled with nonpiezoelectric but with magnetite particles has still short history. With the use of magneto materials, a large magnetic DC bias field is generally required, and it causes big problem on application. The films filled with some magnetite nanoparticles (Fe3O4 and Nickel) are fabricated then examined. It is clearly demonstrated that our films do not require any DC bias. Although linear polarization value is relatively small, the first step of the studies on magnetite nano-filled film is presented.

关键词： electroactive polymers     carbon filling     actuator     nanocarbon     electromechanical coupling     dielectric polymer actuators     polymer actuators     microactuation     magneto-electric effect    

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catalysts derived from zeolitic imidazolate framework@MXene composites for efficient oxidative self-coupling

《化学科学与工程前沿（英文）》 2023年 第18卷 第1期 doi: 10.1007/s11705-023-2378-9

摘要： In this study, we synthesize a catalyst comprising cobalt nanoparticles supported on MXene by pyrolyzing a composite in a N2 environment. Specifically, the composite comprises a bimetallic Zn/Co zeolitic imidazole framework grown in situ on the outer surface of MXene. The catalytic efficiency of the catalyst is tested for the self-coupling of 4-methoxybenzylamine to produce value-added imine, where atmospheric oxygen (1 atm) is used as the oxidant. Based on the results, the catalyst displayed impressive catalytic activity, achieving 95.4% yield of the desired imine at 383 K for 8 h. Furthermore, the catalyst showed recyclability and tolerance toward benzylamine substrates with various functional groups. The outstanding performance of the catalyst is primarily attributed to the synergetic catalytic effect between the cobalt nanoparticles and MXene support, while also benefiting from the three-dimensional porous structure. Additionally, a preliminary investigation of potential reaction mechanisms is conducted.

关键词： MXene     sacrificial template     oxidative self-coupling     Co nanoparticles     imine    

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Thermodynamic and economic analyses of a coal and biomass indirect coupling power generation system

Buqing YE, Rui ZHANG, Jin CAO, Bingquan SHI, Xun ZHOU, Dong LIU

《能源前沿（英文）》 2020年 第14卷 第3期   页码 590-606 doi: 10.1007/s11708-020-0809-6

摘要： The coal and biomass coupling power generation technology is considered as a promising technology for energy conservation and emission reduction. In this paper, a novel coal and biomass indirect coupling system is proposed based on the technology of biomass gasification and co-combustion of coal and gasification gas. For the sake of comparison, a coal and biomass direct coupling system is also introduced based on the technology of co-combustion of coal and biomass. The process of the direct and the indirect coupling system is simulated. The thermodynamic and economic performances of two systems are analyzed and compared. The simulation indicates that the thermodynamic performance of the indirect coupling system is slightly worse, but the economic performance is better than that of the direct coupling system. When the blending ratio of biomass is 20%, the energy and exergy efficiencies of the indirect coupling system are 42.70% and 41.14%, the internal rate of return (IRR) and discounted payback period (DPP) of the system are 25.68% and 8.56 years. The price fluctuation of fuels and products has a great influence on the economic performance of the indirect coupling system. The environmental impact analysis indicates that the indirect coupling system can inhibit the propagation of NO and reduce the environmental cost.

关键词： biomass     indirect coupling system     process simulation     thermodynamic analysis     economic analysis    

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Enhancing the aromatic selectivity of cyclohexane aromatization by CO2 coupling

《化学科学与工程前沿（英文）》 2023年 第17卷 第11期   页码 1801-1808 doi: 10.1007/s11705-023-2325-9

摘要： Improving the aromatic selectivity in the alkane aromatization process is of great importance for its practical utilization but challenge to make because the high H/C ratio of alkanes would lead to a serious hydrogen transfer process and a large amount of light alkanes. Herein, CO2 is introduced into the cyclohexane conversion process on the HZSM-5 zeolite, which can improve the aromatic selectivity. By optimizing the reaction conditions, an improved aromatic (benzene, toluene, xylene, and C9+) selectivity of 48.2% can be obtained at the conditions of 2.7 MPa (CO2), 450 °C, and 1.7 h−1, which is better than that without CO2 (aromatic selectivity = 43.2%). In situ transmission Fourier transform infrared spectroscopy spectra illustrate that many oxygenated chemical intermediates (e.g., carboxylic acid, anhydride, unsaturated aldehydes/ketones or ketene) would be formed during the cyclohexane conversion process in the presence of CO2. 13C isotope labeling experimental results demonstrate that CO2 can enter into the aromatics through the formation of oxygenated chemical intermediates and thereby improve the aromatic selectivity. This study may open a green, economic, and promising way to improve the aromatic selectivity for alkane aromatization process.

关键词： aromatics     carbon dioxide     aromatization     coupling reaction     ZSM-5 zeolite    

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Mild and highly regioselective synthesis of biaryl acids via Rh(I)-catalyzed cross-dehydrogenative coupling

Yun Liu, Youquan Zhu, Chaojun Li

《化学科学与工程前沿（英文）》 2018年 第12卷 第1期   页码 3-8 doi: 10.1007/s11705-017-1693-4

摘要： A mild and efficient synthesis for the biaryl acids via rhodium-catalyzed cross-dehydrogenative coupling reaction has been developed. This novel protocol with sodium chlorite as an oxidant featured many advantages such as mild reaction conditions, high regioselectivity, tolerance of various functional groups, and good to excellent yields.

关键词： biaryl acids     cross-dehydrogenative coupling     rhodium-catalyzed    

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Modeling of specific structure crystallization coupling with dissolution

Yuanhui JI, Hongliang QIAN, Chang LIU, Xiaohua LU, Xin FENG, Xiaoyan JI,

《化学科学与工程前沿（英文）》 2010年 第4卷 第1期   页码 52-56 doi: 10.1007/s11705-009-0301-7

摘要： In this paper, the research framework for specific structure crystallization modeling has been proposed in which four steps are required in order to investigate the rigorous crystallization modeling by thermodynamics. The first is the activity coefficient model of the solution, the second is Solid-Liquid equilibrium, the third and fourth are the dissolution and crystallization kinetics modeling, respectively. Our investigations show that the mechanisms of complex structure formation and microphase transition can be analyzed by combining the dissolution and crystallization kinetics modeling. Moreover, the formation mechanism of the porous KCl has been analyzed, which may provide a reference for the porous structure formation in the advanced material synthesis.

关键词： structure crystallization     activity coefficient     reference     KCl     dissolution    

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A novel structural modification to eliminate the early coupling between bending and torsional mode shapes

Nazim Abdul NARIMAN

《结构与土木工程前沿（英文）》 2017年 第11卷 第2期   页码 131-142 doi: 10.1007/s11709-016-0376-4

摘要： In this paper, a novel structural modification approach has been adopted to eliminate the early coupling between the bending and torsional mode shapes of vibrations for a cable stayed bridge model generated using ABAQUS software. Two lateral steel beams are added to the middle span of the structure. Frequency analysis is dedicated to obtain the natural frequencies of the first eight mode shapes of vibrations before and after the structural modification approach. Numerical simulations of wind excitations are conducted for the 3D model of the cable stayed bridge with duration of 30 s supporting on real data of a strong wind from the literature. Both vertical and torsional displacements are calculated at the mid span of the deck to analyze both the bending and the torsional stiffness of the system before and after the structural modification. The results of the frequency analysis after applying lateral steel beams declared a safer structure against vertical and torsional vibrations and rarely expected flutter wind speed. Furthermore, the coupling between the vertical and torsional mode shapes has been removed to larger natural frequencies magnitudes with a high factor of safety. The novel structural approach manifested great efficiency in increasing vertical and torsional stiffness of the structure.

关键词： aeroelastic instability     structural damping     flutter wind speed     bending stiffness     torsional stiffness    

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Study on System Coupling Interaction of Large-Scale Construction Companies Programme Contracting and

Feng Guo,Tian Huang

《工程管理前沿（英文）》 2015年 第2卷 第2期   页码 137-140 doi: 10.15302/J-FEM-2015022

摘要： Constant changes in the construction market have resulted in individual projects being challenged to meet the long-term growth needs of large construction companies. Change should be based on the construction of this new model project group, to achieve better interaction, and to allow for a more rapid enterprise development. This paper is based on the system coupling analysis of large-scale construction enterprises and construction projects. A clear system presents itself and forms the basis of the system construction, institutional change and mechanism of the path between base construction projects and business growth.

关键词： programme contracting     firm growth     coupling interaction     system     large construction companies    

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Erratum to: Bending and vibration of a discontinuous beam with a curvic coupling under different axial

《机械工程前沿（英文）》 2022年 第17卷 第2期 doi: 10.1007/s11465-022-0709-z

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标题 作者 时间 类型 操作

Microdamage study of granite under thermomechanical coupling based on the particle flow code

期刊论文

Continuous modeling of soil morphology —thermomechanical behavior of embankment dams

Bettina ALBERS, Krzysztof WILMANSKI

期刊论文

Effect of alkyl nitrite decomposition on catalytic performance of CO coupling reaction over supported

Zhenhua LI, Weihan WANG, Dongxue YIN, Jing LV, Xinbin MA

期刊论文

An extended thermo-mechanically coupled algorithm for simulation of superelasticity and shape memory effect

S. HASHEMI,H. AHMADIAN,S. MOHAMMADI

期刊论文

北京市城乡节能节水政策中长期耦合效果分析

刘耕源,胡俊梅,杨志峰

期刊论文

Simulation of steel beam under ceiling jet based on a wind–fire–structure coupling model

期刊论文

Polymer nanocomposites for microactuation and magneto-electric transduction

Kaori YUSE, Benoit GUIFFARD, Rabah BELOUADAH, Lionel PETIT, Laurence SEVEYRAT, Daniel GUYOMAR

期刊论文

catalysts derived from zeolitic imidazolate framework@MXene composites for efficient oxidative self-coupling

期刊论文

Thermodynamic and economic analyses of a coal and biomass indirect coupling power generation system

Buqing YE, Rui ZHANG, Jin CAO, Bingquan SHI, Xun ZHOU, Dong LIU

期刊论文

Enhancing the aromatic selectivity of cyclohexane aromatization by CO2 coupling

期刊论文

Mild and highly regioselective synthesis of biaryl acids via Rh(I)-catalyzed cross-dehydrogenative coupling

Yun Liu, Youquan Zhu, Chaojun Li

期刊论文

Modeling of specific structure crystallization coupling with dissolution

Yuanhui JI, Hongliang QIAN, Chang LIU, Xiaohua LU, Xin FENG, Xiaoyan JI,

期刊论文

A novel structural modification to eliminate the early coupling between bending and torsional mode shapes

Nazim Abdul NARIMAN

期刊论文

Study on System Coupling Interaction of Large-Scale Construction Companies Programme Contracting and

Feng Guo,Tian Huang

期刊论文

Erratum to: Bending and vibration of a discontinuous beam with a curvic coupling under different axial

期刊论文